I have that motherboard running Ubuntu 8.04 amd64. It was really unstable with the F2 firmware that came with it, but since upgrading to the latest firmware it's been fine. Before it wouldn't even get past POST with the virtualisation extensions or Cool&Quiet enabled - I'm now running with virtualisation enabled, but I haven't tried it in any VMs, and I haven't enabled C&Q. I don't have a Black Edition, so I can't say anything about overclocking performance, but all the options are there in the BIOS and it all works on paper.
As for the Catalyst drivers, I haven't got them working in my 64-bit install, but I'm fairly confident it's user error, because I did a fresh install of a clean (albeit 32-bit) OS and the driver worked fine.
I'm not sure whether to recommend the Gigabyte motherboard or not - it works fine for me, and it's great value, but people that dislike them do with a passion.


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and to reply to Kano, I'm getting nervous thinking of buying ATI graphics card... I have always used nVIDIA chips, and it has worked fine all the time, but ofcourse, you get curious about the new AMD opensource-initiative.. 
