When using ATI it's a little awkward at times because the initial setup can be a little bit of trouble. The first step is to confirm the driver is working properly, and to do that you need to run this command from xorg:
if this is working it should output something similar to this: (The sample is for an old system, but current systems have similar outputs )
Code:
display: :0.0 screen: 0
OpenGL vendor string: ATI Technologies Inc.
OpenGL renderer string: Radeon X1600 Series
OpenGL version string: 2.1.7415 Release
This should be enough to confirm that the system has OpenGL Information, however if you want to verify more in depth, use the command "glxinfo"
Now the next step is easy enough... Configure everything to use OpenGL for rendering ( this should provide performance boosts).
However, the only other suggestion is to look into installing the xvba driver for vaapi.