a arch based distro with KDE 4 desktop would be Chakra. I never tried it, because I don't like KDE much.
Kahel OS is also Arch based, and uses the gnome 3 desktop. The last time I tried it was in the beginning of 2010 with gnome 2. It was not a bad distro when I tried it. I think I had it on my computer several month or at least some weeks as primary system.



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