You're not the first one that asked this type of question, and the best answer would be that you should have a look at both of these distributions.
I personally would recommend you to use VirtualBox (or VMware) and have a look at both of them in a virtual machine. The default desktop environment for both of them is Gnome, however their KDE desktops are catching up quite fast. So what about giving Ubuntu with Gnome and the Fedora KDE-Spin a try? If your internet connection is not too slow, just grab both of them and start playing with them in a virtual machine:
VirtualBox
Fedora 8 Live KDE
Ubuntu 7.10


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